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Question

Which of the following compounds will show metamerism ?


A
1 and 2
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B
3 and 4
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C
2 and 3
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D
1 and 4
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Solution

The correct option is A 1 and 2
Metamerism :
Structural isomers in which there is a difference in the relative position of alkyl group around polyvalent atom/functional groups.
In options (1) and (2) the relative position of alkyl groups around the functional group can be different. So, they show metamerism. thus Diethyl thioether(C2H5SC2H5) and Methyl propyl thioether (CH3SC3H7) are metamers.

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