Which of the following compounds will undergo carbylamine reaction?

(C H_{3} C H_{2})_{2} N H

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(C H_{3})_{2} N H

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C_{6} H_{5} N H_{2}

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(C H_{3})_{3} N

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Solution

The correct option is C $C_{6} H_{5} N H_{2}$
Carbylamine reaction is given by only primary amines (both aliphatic and aromatic). In this reaction, a primary amine reacts with chloroform in basic medium, to form a very bad smelling compound, called carbylamine.
$C_{6} H_{5} N H_{2} + C H C l_{3} + K O H \to C_{6} H_{5} N C + K C l + H_{2} O$

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Similar questions

C H_{3} N H_{2}

(C H_{3})_{2} N H

(C H_{3})_{3} N

C_{6} H_{5} N H_{2}

Arrange the following in increasing order of their basic strength:

(i) C₂H₅NH₂, C₆H₅NH₂, NH₃, C₆H₅CH₂NH₂ and (C₂H₅)₂NH

(ii) C₂H₅NH₂, (C₂H₅)₂NH, (C₂H₅)₃N, C₆H₅NH₂

(iii) CH₃NH₂, (CH₃)₂NH, (CH₃)₃N, C₆H₅NH₂, C₆H₅CH₂NH₂.

C H_{3} N H_{2}, (C H_{3})_{2} N H, N H_{3}, C_{6} H_{5} N H_{2}

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