Which of the following compounds yield most stable carbanion after rupture of $(C_{1} C_{2})$ bond

C H_{3} - O | | C 1 C 2 O_{3}

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C H_{3} - O | | C 1 C 2 B r_{3}

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C H_{3} C H_{2} O | | C 1 C 2 C l_{3}

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None of these

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Solution

The correct option is A $C H_{3} - O | | C 1 C 2 O_{3}$
${C O_{3}}^{-}$ carbanion is not possible structure.

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C H_{3} - C | | O - C H_{3} I C H_{3} - C | | O - C | | O - C H_{3} I I C H_{3} - C | | O - C H_{2} - C | | O - C H_{3} I I I

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Which of the following is a metamer of $C H_{3} C H_{2} - S - C H_{2} C H_{3}$ ?

C H_{3} - O | | C - H (i); C H_{3} - O | | C - C H_{3} (i i); E t - O | | C - H (i i i)

C H_{3} - C H_{2} - C H_{2} - O | | C - H (i v); P h - O | | C - C H_{3} (v); P h - O | | C - P h (v i)

C H_{2} = O H | C - C H_{2} - O | | C - C H_{3} ⇌ C H_{3} - O | | C - C H_{2} - O | | C - C H_{3} ⇌ C H_{3} - O H | C = C H - O | | C - C H_{3}

I

I I

I I I

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