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Question

Which of the following contains the same number of molecules?

A
1 g of O2, 2 g of SO2
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B
1 g of CO2, 1 g of N2O
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C
112 ml of O2 at STP, 224 ml of He at 0.5 atm and 273 K
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D
1 g of O2, 1 g of O3
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Solution

The correct options are
A 1 g of O2, 2 g of SO2
B 1 g of CO2, 1 g of N2O
C 112 ml of O2 at STP, 224 ml of He at 0.5 atm and 273 K
For same number of molecules, number of moles should be same.
1 g of O2 corresponds to 132 moles. 2g of SO2 corresponds to 264=132 moles. Thus, they contain same number of molecules.
1 g of CO2 corresponds to 144 moles. 1g of N2O corresponds to 144 moles. Thus, they contain same number of molecules.
112 ml of O2 at STP corresponds to 0.005 moles. 224 ml of He at 0.5 atm and 273 K corresponds to 0.005 moles. Thus, they contain same number of molecules.
1 g of O2 corresponds to 132 moles. 1g of O3 corresponds to =148 moles. Thus, they contain different number of molecules.

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