Which of the following does not evolve oxygen at anodes when electrolysis is carried?
A
dil, H2SO4 with Pt electrode
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B
Fused NaOH with Pt electrode
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C
Acidic water with Pt electrode
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D
dil, H2SO4 with Cu electrode
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Solution
The correct option is A dil, H2SO4 with Cu electrode In the electrolysis of dil. H2SO4 using Cu electrodes, the reaction at anode occurs as:
Cu →Cu2+ + e−
The electrode is not inert an so participates in the reaction. In all other reaction, inert electrode i.e. Pt is used. Thus oxygen is evolved in these reactions.