Which of the following does not give a precipitate of AgCl with AgNO3 solution?
A
[Co(NH3)6]Cl3
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B
[Co(NH3)5Cl]Cl2
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C
[Co(NH3)4Cl2]Cl
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D
[Co(NH3)3Cl3]
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Solution
The correct option is D[Co(NH3)3Cl3] [Co(NH3)3Cl3] does not ionise to furnish Cl− ion as no chlorine atom is present outside the coordination sphere. Evidently, it would not give a white precipitate with AgNO3