Which of the following does not give a precipitate of AgCl with AgN O 3 solution-A- - Co N H 36- Cl 3B- - Co NH 35 Cl - Cl 2C- - Co NH 33 Cl 3-D- - Co NH 34 Cl 2- Cl

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Standard XII

Chemistry

Linkage Isomerism

Which of the ...

Question

Which of the following does not give a precipitate of $A g C l$ with $A g N O_{3}$ solution?

[C o (N H_{3})_{6}] C l_{3}

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[C o (N H_{3})_{5} C l] C l_{2}

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[C o (N H_{3})_{4} C l_{2}] C l

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[C o (N H_{3})_{3} C l_{3}]

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Solution

The correct option is D $[C o (N H_{3})_{3} C l_{3}]$
$[C o (N H_{3})_{3} C l_{3}]$ does not ionise to furnish $C l^{-}$ ion as no chlorine atom is present outside the coordination sphere. Evidently, it would not give a white precipitate with $A g N O_{3}$

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Similar questions

Arrange the following complexes in the increasing order of conductivity of their solution

$[C o (N H_{3})_{3} C l_{3}], [C o (N H_{3})_{4} C l_{2}] C l, [C o (N H_{3})_{6}] C l_{3}, [C o (N H_{3})_{5} C l] C l_{2}$

Q. One mole of the complex with molecular formula

[C o (N H_{3})_{5} C l_{3}]

gives two moles of

A g C l

with excess of

A g N O_{3}

. The complex is

Q. The correct order of the following complexes according to increasing conductivity of their solutions will be:
(i)

[C o (N H_{3})_{3} C l_{3}]

(ii)

[C o (N H_{3})_{4} C l_{2}] C l

(iii)

[C o (N H_{3})_{6}] C l_{3}

(iv)

[C o (N H_{3})_{5} C l] C l_{2}

Q. Assertion :Statement

-

1 :

[C o {(N H_{3})}_{3} C l_{3}]

does not give a white precipitate with

A g N O_{3}

solution. Reason: Statement

-

2 : Chlorine is not present in the ionisation sphere of

[C o {(N H_{3})}_{3} C l_{3}]

Q. One mole of complex compound

C o (N H_{3})_{5} C l_{3}

gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with two moles of

A g N O_{3}

to yeild two moles of

A g C l_{(S)}

. The complex is:

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Which of the following does not give a precipitate of AgCl with AgNO3 solution?

The correct option is D [Co(NH3)3Cl3][Co(NH3)3Cl3] does not ionise to furnish Cl− ion as no chlorine atom is present outside the coordination sphere. Evidently, it would not give a white precipitate with AgNO3

Which of the following does not give a precipitate of $A g C l$ with $A g N O_{3}$ solution?

The correct option is D $[C o (N H_{3})_{3} C l_{3}]$
$[C o (N H_{3})_{3} C l_{3}]$ does not ionise to furnish $C l^{-}$ ion as no chlorine atom is present outside the coordination sphere. Evidently, it would not give a white precipitate with $A g N O_{3}$