Which of the following does not give its oxoacid of central atom on hydrolysis?

SCl₄

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NCl₃

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PCl₅

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AsCl₃

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Solution

The correct option is B
NCl₃

$S C l_{4} + H_{2} O \to H_{2} S O_{3} + H C l N C l_{3} + H_{2} O \to N H_{3} + H O C l P C l_{5} + H_{2} O \to H_{3} P O_{4} + H C l A s C l_{3} + H_{2} O \to H_{3} A s O_{3} + H C l$

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s p^{3}

From the following, no. of compounds which do not hydrolyze

$N F_{3}, N C l_{3}, P C l_{3}, P C l_{5}, C C l_{4}, S i C l_{4}, B i C l_{3}, N a C l, F e C l_{3}$

A l C l_{3}

Among the following, the number of compounds which do not hydrolyze

$N F_{3}, N C l_{3}, P C l_{3}, P C l_{5}, C C l_{4}, S i C l_{4}, B i C l_{3}, N a C l, F e C l_{3}$

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