Which of the following does not have optical isomers ?

[C o (e n)_{3}] C l_{3}

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[C o (N H_{3})_{3} C l_{3}]

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[C o (e n)_{2} C l_{2}] C l

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[C o (e n) (N H_{3})_{2} C l_{2}] C l

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Solution

The correct option is B $[C o (N H_{3})_{3} C l_{3}]$
The complex $[C o (N H_{3})_{3} C l_{3}]$ does not have optical isomers due to presence of an element of symmetry. However, it exists in two geometrical isomers which are cis and trans or fac and mer isomers.

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