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Question

Which of the following does not show positive deviation from Raoult's law?

A
Phenol - aniline
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B
Ethanol - acetone
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C
Acetone - carbon disulphide
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D
Methanol - water
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Solution

The correct option is D Phenol - aniline
In case of negative deviations from Raoult's law, the intermolecular attractive forces between A-A and B-B are weaker than those between A-B and leads to decrease in vapour pressure resulting in negative deviations. An example of this type is a mixture of phenol and aniline.
Hence, option A is correct.

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