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Question

Which of the following does not undergo aldol condensation ?

A
HCHO
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B
CH3CHO
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C
CH3COCH3
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D
CH3CH2CHO
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Solution

The correct option is A HCHO
Carbonyl compounds containing alpha hydrogen atom undergoes aldol condensation reaction. Formaldehyde HCHO does not contain alpha hydrogen atom. Hence, it does not undergo aldol condensation reaction. Instead, it undergoes Cannizzaro reaction.

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