Which of the following double salt does not exist?

{({N H}_{4})}_{2} {S O}_{4} \cdot C u {S O}_{4} \cdot 6 H_{2} O

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{({N H}_{4})}_{2} {S O}_{4} \cdot F e {S O}_{4} \cdot 6 H_{2} O

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{({N H}_{4})}_{2} {S O}_{4} \cdot Z n {S O}_{4} \cdot 6 H_{2} O

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{({N H}_{4})}_{2} {S O}_{4} \cdot N i {S O}_{4} \cdot 6 H_{2} O

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Solution

The correct option is C ${({N H}_{4})}_{2} {S O}_{4} \cdot Z n {S O}_{4} \cdot 6 H_{2} O$
Double salts are the molecular compounds that exists only in crystal lattice and lose their identity on dissolution in water.
The double salt ${({N H}_{4})}_{2} {S O}_{4} \cdot Z n {S O}_{4} \cdot 6 H_{2} O$ does not exist.

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