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Question

Which of the following electrolytes will not be most effective in the coagulation of gold sol?

A
NaNO3
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B
K4[Fe(CN)6]
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C
Na3PO4
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D
MgCl2
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Solution

The correct options are
A NaNO3
B K4[Fe(CN)6]
C Na3PO4
Coagulation is the process by which a colloid precipitates out of a solution. The precipitation is brought about by induced aggregation.
The purpose of coagulation is to make solid, suspended colloidal particles thick. This is done by adding sufficient amount of a cationic coagulant. It helps inneutralization of the suspended particles.
Na loses one electron but Mg loses two electrons. So, Mg is strong cation. So, MgCl2 is used for the coagulation of gold sol.


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