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Question

Which of the following elements does not show allotropy?

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Solution

The trend in allotropy of group 15 elements

In group 15, all the elements show allotropy except nitrogen. Nitrogen does not show allotropy due to its weak NN single bond because of high inter-electronic repulsion of the non-bonding electrons and has less stability to form polymeric structure. Rest elements of group 15, such as phosphorus, arsenic, antimony, and bismuth, show allotropy due to their ability to form stronger single bonds with themselves.

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