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Question

Which of the following expression correctly represents the equivalent conductivity at infinite dilution of Al2(SO4)3?

Given that λAl3+ and λSO24 are the equivalent conductivities at infinite dilution of the respective ions.

A
2λAl3++3λSO24
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B
λAl3++λSO24
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C
(λAl3++3λSO24)×6
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D
13λAl3++12λSO24
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Solution

The correct option is B. λAl3++λSO24

Al2(SO4)32Al3++3SO24

"Kohlrausch's law states that the equivalent conductivity of an electrolyte at infinite dilution is equal to the sum of the conductances of the anions and cations."

λoAl2(SO4)3=2λoAl3++3λoSO24

Since equivalent conductance are given only for cation and anion, the equivalent conductance at infinite dilution is: λAl3++λSO24


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