Which of the following forms ideal solution?

C_{6} H_{5} C l - C_{6} H_{5} B r

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C_{6} H_{6} - C_{6} H_{5} C H_{3}

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Hexane-heptane

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none of these

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Solution

The correct options are
A $C_{6} H_{5} C l - C_{6} H_{5} B r$
B $C_{6} H_{6} - C_{6} H_{5} C H_{3}$
C Hexane-heptane
An Ideal solution is the one which obeys Roault's Law at all concentrations and temperature and during the formation of which no change in enthalpy and volume takes place.
1) $C_{6} H_{5} C l - C_{6} H_{5} B r$ .
2) $C_{6} H_{6} - C_{6} H_{5} C H_{3}$ .
3)Hexane-heptane.
all the three compounds obeys Roault's Law at all concentrations and temperature and during the formation of which no change in enthalpy and volume takes place.

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Column - I	Column - II
a) A nearly ideal solution	p) $H_{2} O + C_{2} H_{5} O H$
b) A solution showing positive deviation	q) $C_{6} H_{6} + C_{6} H_{5} C H_{3}$
c) A solution showing negative deviation	r) $C_{6} H_{6} + C H C l_{3}$
d) An azeotropic mixture	s) $C H_{3} C O C H_{3}$ + $C_{2} H_{5} O H$
	t) $Δ H$ and $Δ V$ are positive
	u) $Δ H$ and $Δ V$ are negative