Which of the following gives Cl2 gas at an anode and H2 gas at cathode on electrolysis?
A
Concentrated solution of NaCl
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B
Molten NaCl
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C
Dilute solution of NaCl
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D
Solid NaCl
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Solution
The correct option is A Concentrated solution of NaCl The electrolysis of a concentrated aqueous solution of NaCl gives Cl2 gas at the anode and H2 gas at the cathode.
Reduction of water at cathode: 2H2O(l)+2e−→H2(g)+2OH−(aq)
Oxidation of chloride ions at anode: 2Cl−(aq)→Cl2(g)+2e−