Which of the following Grignard reagents is not possible ?

H S - C H_{2} - C H_{2} - C H_{2} M g B r

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H O - C H_{2} - C H_{2} - C H_{2} M g B r

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N H_{2} - C H_{2} - C H_{2} M g B r

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All of these

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Solution

The correct option is D All of these
Grignard agent should not have any acidic hydrogen as it gets destroyed when there is any acidic hydrogen is there on the compound.

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C H_{3} - C H_{2} - C I

C H_{3} - C H_{2} - C H_{2} - N H_{2}

C_{6} H_{5} - C H_{2} - C I

C_{6} H_{5} - C H_{2} - C H_{2} - N H_{2}

C H_{2} = C H - . . N H - C H_{3}

C H_{2} = C H - . . O . . - C H_{3}

C H_{2} = C H - . . O . . - C H = C H_{2}

C H_{2} = C H - N H_{2}

C H_{3} - C H_{2} - C H_{2} - C O - C l \to C H_{3} - C H_{2} - C H_{2} - C H O

N H_{2} - C H_{2} - C H_{2} - C H_{2} - C O O H

C H_{3} C H_{2} B r + H S^{⊖} \to C H_{3} C H_{2} S H + B r^{⊖}

{(C H_{3})}_{2} C = C H_{2} + H C l \to {(C H_{3})}_{2} (C l) C - C H_{3}

{(C H_{3})}_{3} C - C H_{2} O H + H B r \to {(C H_{3})}_{2} C (B r) C H_{2} C H_{3}

C H_{3} C H_{2} B r + H O^{⊖} \to C H_{2} = C H_{2}

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