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Question

Which of the following halide is/are stable?

A
NF3
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B
PCl3
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C
BiF3
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D
All of the above.
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Solution

The correct option is D All of the above.
All the trihalides of grouyp 15 elements are stable except NX3. Only NF3 is stable​ among all the​ halides of nitrogen.
The reason for the unstability of other trihalides are the bigger size of halogen atom as compared to nitrogen atom. Due to larger size difference in N and halogen the NX bond becomes weaker hence compound become unstable.
​Hence, option (d) is the correct answer.

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