Which of the following halides is inert towards hydrolysis at room temperature?

{S i C l}_{4}

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{P C l}_{3}

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{N C l}_{3}

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{N F}_{3}

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Solution

The correct option is D ${N F}_{3}$
Hydrolysis takes place through the coordination with lone pair of electron of water molecule. But neither nitrogen, nor fluorine have vacant d-orbital for coordination. Hence $N F_{3}$ behaves as inert towards hydrolysis.

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Similar questions

Among the following, the number of compounds which do not hydrolyze

$N F_{3}, N C l_{3}, P C l_{3}, P C l_{5}, C C l_{4}, S i C l_{4}, B i C l_{3}, N a C l, F e C l_{3}$

From the following, no. of compounds which do not hydrolyze
$N F_{3}, N C l_{3}, P C l_{3}, P C l_{5}, C C l_{4}, S i C l_{4}, B i C l_{3}, N a C l, F e C l_{3}$ ___

C C l_{4}

is inert towards hydrolysis but

S i C l_{4}

is readily hydrolysed because:

Q. When

N F_{3}

undergoes hydrolysis at room temperature, the product is :

Q. Which of the following halides cannot be hydrolyzed?

(I)

T e F_{6}

, (II)

S F_{6}

, (III)

N C l_{3}

, and (IV)

N F_{3}

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Which of the following halides is inert towards hydrolysis at room temperature?

The correct option is D NF3Hydrolysis takes place through the coordination with lone pair of electron of water molecule. But neither nitrogen, nor fluorine have vacant d-orbital for coordination. Hence NF3 behaves as inert towards hydrolysis.

The correct option is D ${N F}_{3}$
Hydrolysis takes place through the coordination with lone pair of electron of water molecule. But neither nitrogen, nor fluorine have vacant d-orbital for coordination. Hence $N F_{3}$ behaves as inert towards hydrolysis.