Which of the following halides react(s) with $A g N O_{3 (a q)}$ to give a precipitate that dissolves in $N a_{2} S_{2} O_{3 (a q)}$
(IIT-JEE, 2012)

HCl

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HBr

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Solution

The correct option is D HI
$A g N O_{3} + H C l \to A g C l ↓$
$A g N O_{3} + H B r \to A g B r ↓$
$A g N O_{3} + H l \to A g I ↓$
All these precipitates will get dissolved in hypo $(N a_{2} S_{2} O_{3})$ forming complex, $N a_{3} [A g (S_{2} O_{3})_{2}]$

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