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Question

Which of the following has a zero dipole moment?

A
ClF
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B
PCl3
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C
SiF4
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D
CFCl3
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Solution

The correct option is D SiF4
In SiF4 molecule, with tetrahedral geometry, all the four SiF bond dipoles cancel each other. Hence, there is zero net dipole moment.
On the other hand, in all other molecules, the individual bond dipoles do not cancel each other. Hence, they have non zero resultant dipole moment.

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