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Question

Which of the following has highest boiling point?


A

Ethanol

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B

Propane

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C

Pentanol

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D

All have same

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Solution

The correct option is C

Pentanol


The decreasing order of boiling points is: Pentanol > Ethanol > Propane

Pentanol and ethanol have H-bonding, but molecular mass of pentanol is more than ethanol, so it has high boiling point. Propane has the least boiling point due to non-polar character and weak van der Waals forces of attraction.


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