Which of the following has highest electron gain enthalpy ?
A
F
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B
Cl
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C
Br
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D
I
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Solution
The correct option is BCl Although fluorine is most electronegative element but chlorine has more electron gain enthalpy. This is because of the small size of the fluorine so addition of electron is not favorable process because repulsion between the electrons takes place.
So electron gain enthalpy chlorine is more than the other elements.