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Question

Which of the following has the highest molar conductivity?

A
[Co(NH3)6]Cl3
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B
[Co(NH3)5Cl]Cl2
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C
[Co(NH3)4Cl2]Cl2
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D
[Co(NH3)3Cl3]
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Solution

The correct option is A [Co(NH3)6]Cl3
Higher number of ions ensures higher molar conductivity. On dissociation of [Co(NH3)6]Cl3, there will be four ions in the solution.

3Cl and [Co(NH3)6]3+

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