The correct option is A 4s1
Consider the options:-
A) 4s1- Since it has only one electron, it can be easily removed. Due to shielding effect, the energy is less.
B) 3d2- The I.E is considerable. The energy will be greater than that of 4s1 because of lesser shielding effect.
C) 3p6- Fully filled orbital, high value of I.E.
D) 2p6- Fully filled orbital, high value of I.E.
Hence, option A is the right answer.