The correct option is C Fe3+
Ground state electronic configuration of Fe = [Ar]3d6 4s2
So, Fe has 4 unpaired electrons.
Fe2+=[Ar]3d6 4s0
So, Fe2+ has 4 unpaired electrons.
Fe3+=[Ar]3d5 4s0
So, Fe3+ has 5 unpaired electrons.
Fe4+=[Ar]3d4 4s0
So, Fe4+ has 4 unpaired electrons.