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Question

Which of the following has the same value as ΔfH , CO
a. 12ΔfH(CO2)
b. 12ΔcH(graphite)
c. ΔfH(CO2)ΔfH(graphite)
d. ΔcH(graphite)ΔcH(CO)?

A
a
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B
b
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C
c
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D
d
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Solution

The correct option is B d
As we know,
C(graphite)+O2(g)CO2(g);ΔcH=x kJ................1

CO+1/2O2(g)CO2(g); ΔcH (CO)=z kJ.......................2


Equation (1)-(2) gives (3) eqaution.

C(graphite)+1/2O2(g)CO(g); ΔfH(CO)=y kJ.......................3


From these equations, it can be seen that

ΔfH (CO) = ΔcH(graphite)ΔcH(CO)

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