Which of the following has the shortest C−Cl bond?
A
Cl−CH=CH2
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B
Cl−CH=CH−CH3
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C
Cl−CH=CH−OCH3
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D
Cl−CH=CH−NO2
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Solution
The correct option is DCl−CH=CH−NO2 There is extended conjugation present in option (d), which will reduce the length of C−Cl bond to the greatest extent which can be represented as follows: