Which of the following has zero dipole moment?

C l F

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P C l_{3}

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S i F_{4}

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C F C l_{3}

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Solution

The correct option is C $S i F_{4}$
$S i F_{4}$ has regular tetrahedron geometry. Even though $S i - F$ bonds were polar, net dipole moment is zero because resultant of vector sum of any three bonds will be balanced by fourth one.

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