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Question

Which of the following have identical bond order?


(I) CN− (II) O−2
(III) NO+ (IV) CN+

A
I, III
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B
II, IV
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C
I, II, III
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D
I, IV
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Solution

The correct option is B I, III
CN - 14 electrons (6 from carbon, 7 from nitrogen, add 1 for negative charge)

NO+ - 14 electrons (8 from oxygen, 7 from nitrogen, subtract 1 for positive charge)

CN+ - 12 electrons (6 from carbon, 7 from nitrogen, subtract 1 for positive charge)

O2 - 17 electrons (8 from each oxygen, add 1 for negative charge).

Species containing the same number of electrons have the same bond order.

Therefore, option A is correct.

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