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Question

Which of the following hydrides has the lowest boiling point ?

A
AsH3
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B
SbH3
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C
PH3
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D
NH3
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Solution

The correct option is B SbH3
As we move from top to bottom in the hydrides of a particular group, the boiling point increases as the molecular weight increases (as the magnitude of van der Waal's force increase), hence, ammonia (NH3) should have the least boiling point.
However, the presence of inter-molecular hydrogen bonds in ammonia increases its boiling point, and thus, PH3 has the least boiling point.

Hence, option C is correct.

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