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Question

Which of the following hydrocarbons can decolorize the alkaline potassium permanganate solution?

A
C2H6
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B
C3H8
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C
C5H12
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D
C3H6
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Solution

The correct option is C C3H6
C3H6 Propene readily reacts with alkaline KMnO4 to form propenol. One hydroxyl group attaches to each carbon on either side of the carbon - carbon double bond. KMnO4 is first reduced to MnO42, a dark green solution and is then furthur reduced to MnO2, a dark brown precipitate, which is further reduced to Mn+2ions.
Alkanes are saturated hydrocarbons, as they are bonded by Hydrogen atoms, and are fully stable, participate in few reactions.

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