Which of the following ion has smallest ionic radius
Lets calculate the number of electrons :
K+ → 18 electrons
Ca2+ → 18 electrons
Ti3+ → 18 electrons
Ti4+ → 18 electrons
So, therefore, they all are isoelectronic species.All are cations. Size of the cation decreases with increase in charge on it.Therfore correct optiopn is (d)