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Unsaturated Hydrocarbons

Which of the ...

Question

Which of the following is a $1^{o}$ amine?

(C H_{3})_{3} C N H_{2}

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C_{6} H_{5} N H C H_{3}

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C H_{3} N H C H (C H_{3})_{2}

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(C H_{2} C H_{2})_{2} N C H_{3}

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Solution

The correct option is A $(C H_{3})_{3} C N H_{2}$
In a one degree amine, only one hydrogen atom of $N H_{3}$ is replaced by alkyl group.
So option (a) is correct because one of the hydrogens has been replaced by $(C H_{3})_{3} C -$ group.
General formula for primary amine is $R N H_{2}$
The kind of alkyl group does not matter in deciding the type of amine, what matters is the number of hydrogen that are replaced.

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