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Question

Which of the following is a likely product of the alkylation of ammonia and amines with alkyl halide?

A
Primary amine
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B
Secondary amine
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C
Tertiary amine
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D
All of the above
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Solution

The correct option is D All of the above
When a ammonia acts as the nucleophile, a primary amine is generated.
RX+NH3RNH2+HX 1oAmine 2oAmine
When a primary and secondary amine acts as the nucleophile, a secondary and tertiary amine is generated respectively.
RX+RNH2RNHR+HX 1oAmine 2oAmine
RX+RR′′NHRNRR′′+HX 2oAmine 3oAmine
Hence option (d) is correct.

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