The correct option is C Acetone and CHCl3
(a) n-hexane and n-heptane
(b) Bromoethane and Chloroethane
Both are ideal solutions.
An ideal solution obeys Raoult's law at all temperatures and pressures.
The solute-solute and solvent-solvent interactions are almost similar to solute-solvent interactions. No association or dissociation takes place. It does not form an azeotrope mixture.
For (c): acetone and CHCl3 are the non-ideal solution and shows negative deviation from Raoult's law