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Question

Which of the following is added to purify phosphine gas?

A
HI
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B
FeCl3
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C
CaCN2
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D
H2O
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Solution

The correct option is A HI
When pure, it is non inflammable but becomes inflammable owing to the presence of P2H4 or P4 vapours. To purify it from the impurities, it is absorbed in HI to form phosphonium iodide (PH4I) which on treating with KOH gives off phosphine. PH4I + KOHKI + H2O + PH3

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