The correct option is B Copper sulphate solution acidified with sulphuric acid
In the electrolytic refining of copper, impure copper is made the anode, a thin sheet of pure copper is made the cathode and a solution of copper sulphate acidified by sulphuric acid is used as the electrolyte.
Anode:
Cu→Cu2++2e−
Cathode:
Cu2++2e−→Cu