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Question

Which of the following is an electron-deficient compound?

A
NaBH4
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B
CO2
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C
B2H6
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D
Al2Cl6
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Solution

The correct option is D B2H6
The BHB bridging bonds are 3c2e bonds and not conventional 2c2e (two-center-two-electron) bonds. B has only three valence e- and cannot form four 2c2e bonds and hence is termed electron deficient.
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