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Question

Which of the following is an example of nucleophilic addition to acetaldehyde?

A
Acetal formation
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B
Cyanohydrin formation
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C
Bisulphite adduct
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D
All of the above
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Solution

The correct option is D All of the above
Out of the four choices a,b and c are examples of nucleophilic addition reactions.

A nucleophilic addition reaction is an addition reaction where a chemical compound with an electron deficient or electrophilic double or triple bond, a π bond reacts with electron-rich reactant, termed a nucleophile, with disappearence of the double bond and creation of two new single or σ bond . With a corbonyl compound as an electrophile, the nucleophile can be:
  • An alcohol in acetalisation to an acetal.
  • A cyanide anion in cyanohydrin reaction forming a cyanohydrin product
  • A sulfur ion from sodium bisulfite which forms a bisulfite adduct with aldehyde groups.
Hence, the correct answer is option (d).

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