The correct option is D Respiration
Exothermic reactions give off heat when the reaction happens. If this happens in a solution, it usually makes the solution mixture warm.
When ammonium chloride is dissovled in water, it gets cold. Water absorbs heat to evaporate, melting of ice requires a heat input too - all of these are endothermic reactions.
Respiration produces heat - this is an exothermic process.