Which of the following is/are responsible for the higher boiling points of aldehydes and ketones compared to ethers and hydrocarbons of comparable molecular mass?
A
Intermolecular dipole-dipole interactions between opposite ends of C=O dipoles.
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B
Intermolecular hydrogen bonds.
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C
Dipole induced dipole interactions.
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D
All of these.
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Solution
The correct option is A Intermolecular dipole-dipole interactions between opposite ends of C=O dipoles. Intermolecular dipole-dipole interactions between opposite ends of C=O dipoles are responsible for the higher boiling points of aldehydes and ketones compared to ethers and hydrocarbons of comparable molecular mass.