The correct option is D C6H6
C6H6 belongs to Aromatic hydrocarbons having general formula Cn,H2n−6y (where y: no. of benzene rings, n≥6 )
If n=6,y=1 then CnH2n−6y become C6H6
∴C2H2 belongs to alkynes having general formula CnH2n−2.
C3H8 belongs to alkanes having general formula CnH2n+2
C5H12 belongs to alkanes having general formula CnH2n+2