Which of the following is coloured tetrahedral complex species?

[C u (P P h_{3})_{4}]^{+}

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[Z n (H_{2} O)_{6}]^{2 +}

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[C u (N H_{3})_{4}] S O_{4}

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M n O_{4}^{-}

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Solution

The correct option is D $M n O_{4}^{-}$
$(A) [C u (P P h_{3})_{4}]^{+} \to Tetrahedral P P h_{3} is a strong field ligand. d^{10} configuration, it is colorless (B) [Z n (H_{2} O)_{6}]^{2 +} \to Octahedral complex (C) [C u (N H_{3})_{4}] S O_{4} \to Square plannar ; It is due to the transfer of one lectron from 3d orbital to higher orbital resulting d s p^{2} hybridization. So, the structure is square plannar. (D) M n O_{4}^{-} \to d^{3} S, Tetrahedral complex; purple coloured due to LMCT$

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