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Question

Which of the following is correct value of x in Cr(CO)x?

A
2
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B
4
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C
6
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D
Unpredictable
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Solution

The correct option is C 6
Given, Cr(CO)x
Here, Cr has zero oxidation state,
as has zero oxidation state in the compound
So at zero oxidation state the Electronic configuration of Cr is
[Ar]4s3d5
that means Cr has 6 valencies, as Cr in this state is stable due to half filled orbitals.
Now, for 6 valencies, 6 CO is required.
Therefore x=6
The compound is Cr(CO)6

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