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Question

Which of the following is incorrect statement regarding compound Cl2O6?

A
In covalent (gaseous) state, each Cl atom has a hybridisation of sp3 in Cl2O6
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B
Cl2O6 exists as ClO+2 and ClO4 in ionic form
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C
In ionic form of Cl2O6, hybridisation of Cl atoms is sp2 and sp3
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D
In ionic form of Cl2O6, hybridisation of both the Cl atoms is sp3
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Solution

The correct option is D In ionic form of Cl2O6, hybridisation of both the Cl atoms is sp3
In covalent form, Cl2O6 have a hybridisation of sp3 for each Cl atom since chlorine atom forms 4 sigma bonds


In ionic bond, Cl2O6 exists as ClO+2 and ClO4 since ClO+2 have a steric number of 3 so hybridisation is sp2 and ClO4 has a hybridisation of sp3

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