The correct option is B (iv)
Water of crystallization refers to the number of water molecules present in the salt.
The chemical formula for the given compounds are
Blue vitriol - CuSO4.5H2O , water of crystallization is 5.
Washing soda - Na2CO3.10H2O, water of crystallization is 10.
Gypsum - CaSO4.2H2O, water of crystallization is 2
Baking soda - NaHCO3.It has zero water molecules.
Hence, the correct choice is option (iv)