Solution:
potassium chlorate, or KClO3, undergoes thermal decomposition to form potassium chloride,KCL, and oxygen gas,O2.
Decomposition reaction
will leave behind products that are as stable as possible. Heat is used
to break the bonds of a compound, after which new bonds will be formed
between the elements that formed the original compound. In the case of potassium chlorate,intense heating will produce a very stable ionic compound, potassium chloride, in solid state.
Hence (4) reaction is irreversible