The correct option is A CaCO3(s)+HCl(aq)→
In laboratory, CO2 is prepared by the action of dilute HCl on CaCO3
CaCO3(s)+HCl(aq)→CO2(g)+H2O(l)+CaCl2(aq)
Reaction (b) is a industrial method. Here, the CO2 is produces as a by-product during the manufacture of CaO
CaCO3(s)→CaO(s)+CO2(g)
In reaction (c), methane gas is highly inflammable so it is not used in laboratory for preparation of CO2.
Thus, option (a) is correct.