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Question

Which of the following is liable to be oxidised by periodic acid ?


A

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B

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C

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D

All the three

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Solution

The correct option is D

All the three


Compounds containing two or more OH or > C = O groups, or - OH and > C = O on adjacent carbon atoms are oxidisable. Positive oxidation by periodic acid can be confirmed by carrying out oxidation in presence of AgNO3 when white precipitate of AgIO3 is formed.


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